Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1315291 | Journal of Fluorine Chemistry | 2010 | 6 Pages |
Abstract
The pKa values of a series of fluoroalkanesulfonylamides were measured by potentiometric titration. Different kinds of alkyl halides and tosylates were employed to investigate the nucleophilicity of fluoroalkanesulfonylamides. Fluoroalkanesulfonylamides with longer fluoroalkyl chain have weaker nucleophilicity.
Graphical abstractThe pKa values of a series of fluoroalkanesulfonylamides were measured by potentiometric titration. Different kinds of alkyl halides and tosylates were employed to investigate the nucleophilicity of fluoroalkanesulfonylamides. Fluoroalkanesulfonylamides with longer fluoroalkyl chain have weaker nucleophilicity.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Cheng-Pan Zhang, Zong-Ling Wang, Qing-Yun Chen, Chun-Tao Zhang, Yu-Cheng Gu, Ji-Chang Xiao,