Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1315314 | Journal of Fluorine Chemistry | 2006 | 4 Pages |
Abstract
Hydroboration of fluorinated styrenes with common hydroborating agents results in polymerization. However, regioselective hydroboration has been achieved by utilizing iodoborane-dimethyl sulfide. A series of fluorinated β-phenethyl alcohols and amines were synthesized via this methodology.
Graphical abstractA simple and highly regioselective preparation of β-fluoroaryl organoboranes and their conversion to the corresponding fluorinated alcohols and amines in very high yields has been described. Figure optionsDownload full-size imageDownload as PowerPoint slide
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
P. Veeraraghavan Ramachandran, Sateesh Madhi, Martin J. O’Donnell,