| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1315383 | Journal of Fluorine Chemistry | 2006 | 6 Pages |
The reactions of 3,3-difluoro-1-iodo-2-phenylcyclopropene with thiolate ions (with a molar ratio of 1:1) were carried out in laboratory illumination to give the corresponding substituted product. The presence of p-dinitrobenzene (p-DNB) or hydroquinone (HQ) as well as darkness significantly suppressed the reaction. ESR trapping experiments also evidenced the existence of fluorinated radical. All these results demonstrate the reaction involved a vinylic saturated alkyl and aromatic halides (SRN1) mechanism.
Graphical abstractThe reactions of 3,3-difluoro-1-iodo-2-phenylcyclopropene with thiolate ions (with a molar ratio of 1:1) are demonstrated involving a vinylic SRN1 mechanism by inhibition experiments and ESR spectrum.Figure optionsDownload full-size imageDownload as PowerPoint slide
