| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1315450 | Journal of Fluorine Chemistry | 2008 | 7 Pages |
Abstract
Certain hydrofluorocarbons (HFC) stable towards the strong Lewis acid, antimony pentafluoride, were found to function as a solvent for this aggressive reagent. CF3CF2CH2F (HFC-236cb) was demonstrated to be an excellent solvent for SbF5 and was used for the generation of stable polyfluorinated benzyl and allyl cations. Using this solvent 1-methoxypentafluoroallyl cation and RFOCFCFCF2+ (RF = n-C3F7 and n-C4F9), were generated and characterized by NMR spectroscopy.
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Viacheslav A. Petrov, Alexander Marchione, Will Marshall,