| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1315593 | Journal of Fluorine Chemistry | 2007 | 9 Pages |
The review gives a short survey of some developments in the synthetic chemistry of organoaluminum fluorides. Into the focus is brought the Janus-faced Lewis base–Lewis acid Al compound, group 13 difluorodiorganometalates, fluorine functionalized carbaalane derivatives, fluorination of aluminum imide clusters, diamidoaluminum fluoride, and some group 13 β-diketiminate mono- and difluorides.
Graphical abstractThe figure shows the Lewis base–Lewis acid Al compound, [LAlB(C6F5)3] (L = HC{(CMe)(2,6-iPr2C6H3N)}2], with a donor Al → B bond and simultaneously an acceptor Al → F bond. Like the Roman god Janus, who has two faces in opposite directions that symbolizes two different scenarios. Figure optionsDownload full-size imageDownload as PowerPoint slide
