| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1315606 | Journal of Fluorine Chemistry | 2007 | 4 Pages |
Abstract
A representative series of (organoethynyl)difluoroboranes RCCBF2 (RC4H9, (CH3)3C, CF3, C3F7, (CF3)2CF, CF3CFCF, C4F9CFCF, C6F5) was prepared by abstraction of fluoride from the corresponding K[RCCBF3] salts with BF3 in appropriate solvents (1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluorobutane, or dichloromethane).
Graphical abstractA well feasible and general route to (organoethynyl)difluoroboranes, RHCCBF2, and their perfluorinated analogues, RFCCBF2.Figure optionsDownload full-size imageDownload as PowerPoint slide
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Vadim V. Bardin, Nicolay Yu. Adonin, Hermann-Josef Frohn,