| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1315614 | Journal of Fluorine Chemistry | 2007 | 8 Pages |
Cycloaddition reactions of fluorinated 1,3,4-oxadiazoles with conjugated and unconjugated dienes was studied. The reactions resulted in the formation of products of double cycloaddition (7-oxabicycloheptane type compounds), along with products of intramolecular cycloaddition (oxatricyclic and oxatetracyclic compounds). The structure of 4-(trifluoromethyl)-2-ethoxycarbonyl-1,6-dimethyl-3-oxatricyclo[2.2.1.02,6]heptane was confirmed by single crystal X-ray diffraction analysis.
Graphical abstractA number of acyclic and cyclic dienes, either conjugated or unconjugated, were studied in cycloaddition reactions with fluorinated 1,3,4-oxadiazoles. The reactions resulted in the products of both double cycloaddition (7-oxabicycloheptane compounds) and intramolecular cycloaddition (oxatricyclic and oxatetracyclic compounds). The structure of 4-(trifluoromethyl)-2-ethoxycarbonyl-1,6-dimethyl-3-oxatricyclo[2.2.1.02,6]heptane was confirmed by single crystal X-ray diffraction analysis. Figure optionsDownload full-size imageDownload as PowerPoint slide
