| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1315660 | Journal of Fluorine Chemistry | 2006 | 9 Pages |
The fluorine-containing dicobalthexacarbonyl complex, prepared readily from γ-fluoroalkylated propargyl acetates and Co2(CO)8, reacted smoothly with various nucleophiles at the propargylic position, followed by oxidative decomplexation under the influence of Fe(NO3)3, to afford fluoroalkylated alkynes bearing various types of alkyl side chains in good to high yields.
Graphical abstractVarious fluorine-containing dicobalthexacarbonyl complexes, prepared readily from γ-fluoroalkylated propargyl acetates and Co2(CO)8, reacted smoothly with various nucleophiles at the propargylic position, followed by oxidative decomplexation under the influence of Fe(NO3)3, to afford fluoroalkylated alkynes bearing various types of alkyl side chains in good to high yields. Figure optionsDownload full-size imageDownload as PowerPoint slide
