Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1315689 | Journal of Fluorine Chemistry | 2006 | 4 Pages |
Abstract
Several fluorinated alkenes were prepared from known ethyl (R)-2-fluoro-4,5-dihydroxyisopropylidine-2-pentenoate (1). The fluoroalkenoates were tested as dienophiles with several dienes and showed cycloaddition only with the very reactive diene, 1,3-diphenylisobenzofuran (5). Fluorobutenolide 2 reacted with 5 to produce the endo-syn adduct 9 in a highly stereoselective manner.
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Timothy B. Patrick, Cynthia Fianu, Eric Pak, Kasey Zaksas, Bradley E. Neal,