Article ID Journal Published Year Pages File Type
1315705 Journal of Fluorine Chemistry 2006 4 Pages PDF
Abstract

A variety of alkenes and α,β-unsaturated carbonyls were reacted with BrF3 to form vicinal bromofluoro compounds. In most cases, the reactions followed a Markovnikov regioselectivity and anti-addition stereospecifity. They proceeded well even with deactivated olefins in around 70% yield. The bromofluoro compounds served as starting materials for the synthesis of fluoroalkenes and fluoroamines.

Graphical abstractA variety of alkenes and α,β-unsaturated carbonyls were reacted with BrF3 to form vicinal bromofluoro compounds. The reactions were regioselctive and anti-addition stereospecific. The bromofluoro compounds served as starting materials for the synthesis of fluoroalkenes and fluoroamines. Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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