Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1316074 | Journal of Inorganic Biochemistry | 2015 | 12 Pages |
Abstract
Linkage isomers of composition X-M-A-M-A-M-X (M = trans-a2PtII, a = am(m)ine; A = 9-alkyladenine; X = other nucleobase or NH3/amine) display differences in pKa values of the first A to undergo deprotonation at the exocyclic amino group, depending on the central cross-linking pattern and the rotamer state of the adenines.68
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Marc Sven Lüth, Eva Freisinger, Gunnar Kampf, Marta Garijo Anorbe, Rolf Griesser, Bert P. Operschall, Helmut Sigel, Bernhard Lippert,