Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1316624 | Journal of Inorganic Biochemistry | 2010 | 5 Pages |
Abstract
Reaction of the known titanocene Y 2 with methyl lithium at −15 °C yields bis-[(p-methoxybenzyl)cyclopentadienyl]titanium(IV) dimethyl (dimethyl titanocene Y, 3), a hitherto unknown, surprisingly robust titanium (IV) dimethyl species. Dimethyl titanocene Y was utilized in the preparation of several bis-[(p-methoxybenzyl)cyclopentadienyl]titanium(IV) dicarboxylates by the reaction with the free carboxylic acids in fair to good yields. Cytotoxicity of all new compounds has been estimated in Hela S3 cells.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Timo A. Immel, Josefine T. Martin, Christoph J. Dürr, Ulrich Groth, Thomas Huhn,