Article ID Journal Published Year Pages File Type
1316624 Journal of Inorganic Biochemistry 2010 5 Pages PDF
Abstract

Reaction of the known titanocene Y 2 with methyl lithium at −15 °C yields bis-[(p-methoxybenzyl)cyclopentadienyl]titanium(IV) dimethyl (dimethyl titanocene Y, 3), a hitherto unknown, surprisingly robust titanium (IV) dimethyl species. Dimethyl titanocene Y was utilized in the preparation of several bis-[(p-methoxybenzyl)cyclopentadienyl]titanium(IV) dicarboxylates by the reaction with the free carboxylic acids in fair to good yields. Cytotoxicity of all new compounds has been estimated in Hela S3 cells.

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Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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