Article ID Journal Published Year Pages File Type
1317646 Journal of Inorganic Biochemistry 2006 7 Pages PDF
Abstract

Amidato-N ligands are normally viewed as classic, strongly σ-donating, innocent ligands. However, when coordinated to high-valent transition metal centers, tetraamidomacrocyclic ligands are often substantially noninnocent, i.e., exhibit radical character involving the amido π-systems. Even the so-called MAC∗ ligand, generally considered to be an innocent ligand, is noninnocent in several of its known complexes.

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Physical Sciences and Engineering Chemistry Inorganic Chemistry
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