Article ID Journal Published Year Pages File Type
1320792 Journal of Organometallic Chemistry 2015 5 Pages PDF
Abstract

•Rh(I) and Ir(I) complexes bearing imidazo[1,5-a]pyridine-1-ylalkyl alcohol as chelating NˆO-monoanionic ligands have been prepared.•Their spectroscopic properties and structures were determined based on IR and NMR spectra and X-ray analyses.•The Rh(I) complexes were used as catalysts for the E-selective hydrosilylation of alkynes.

Rh(I) and Ir(I) complexes bearing imidazo[1,5-a]pyridine-1-ylalkyl alcohol as chelating NˆO-monoanionic ligands were prepared as thermally stable compounds. Their spectroscopic properties and structures were determined based on IR and NMR spectra and X-ray analyses. The Rh(I) complexes were used as catalysts for the hydrosilylation of alkynes. The catalytic activities of the complexes were highly influenced by the substituents on their aromatic rings. Highly E-selective formation of vinylsilanes was achieved at higher temperatures for longer reaction times.

Graphical abstractRh(I) and Ir(I) complexes bearing imidazo[1,5-a]pyridine-1-ylalkyl alcohol as chelating NˆO-monoanionic ligands were prepared as thermally stable compounds. Their spectroscopic properties and structures were determined based on IR and NMR spectra and X-ray analyses. The Rh(I) complexes were used as catalysts for the hydrosilylation of alkynes. The catalytic activities of the complexes were highly influenced by the substituents on their aromatic rings. Highly E-selective formation of vinylsilanes was achieved at higher temperatures for longer reaction times.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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