Article ID Journal Published Year Pages File Type
1321556 Journal of Organometallic Chemistry 2013 5 Pages PDF
Abstract
Cycloruthenates trans-[Ru(nabhR)(PPh3)2Cl] are reported. The molecular structures of the one-electron paramagnetic and redox active complexes are established by EPR and X-ray crystallography. Regioselective ortho-ruthenation of 1-naphthalenyl in (nabhR)2− leads to its CNO pincer like binding mode and formation of 5,5-fused chelate rings at the trivalent low-spin metal centre.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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