| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1321952 | Journal of Organometallic Chemistry | 2013 | 6 Pages |
Abstract
⺠Unactivated alkenes react with n-alkyl Grignard reagents in the presence of TaCl5. ⺠[(2Râ²,3R)- and (2R,3R)-disubstituted]-n-butylmagnesiums are the final products. ⺠β,βâ²-Dialkyl substituted tantalacyclopentanes are proposed as key intermediates. ⺠Good to high product yields (up to 90%) are obtained in tetrahydrofuran.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Rifkat M. Sultanov, Ruslan R. Ismagilov, Natal'ya R. Popod'ko, Artur R. Tulyabaev, Usein M. Dzhemilev,