Article ID Journal Published Year Pages File Type
1321994 Journal of Organometallic Chemistry 2015 9 Pages PDF
Abstract

•Calcium apatites CaII10(PO4)6X2 (X = OH, F) are tunable solid catalysts.•Apatites surfaces can be modified by adsorbing organometallic molecules and salts.•Apatites are good and cheap catalysts for many organic reactions.

The development of green and sustainable chemistry is one of the most exciting challenges in modern chemistry. In this way, design of new catalysts for heterogeneous processes is of prime importance and plays a key role to reduce the impact of chemistry on the environment.Our approach to green chemistry deals with the use of an inexpensive suitable and recyclable material namely the apatite's family. Apatites, in which the composition and surface properties can be tuned, are themselves catalysts or can be used as support for catalytic centres in many organic reactions. In this review, we describe the state of the art in this emerging field.

Graphical abstractView of a FAp (left) and Ru-FAp (right)Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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