| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1322005 | Journal of Organometallic Chemistry | 2015 | 10 Pages |
Abstract
Low temperature protonation (â80°C) of a Pt-vinyl complex, (Tpâ²)Pt(CHCH2)(Me)2, generated a small amount of an ethylidene Pt complex, [(Tpâ²)Pt(CH(CH3)Me2][B(ArF)4] as monitored by NMR. Warming the reaction to â40°C results in reductive elimination to form a new C-C bond in a Pt(II) propylene adduct, [κ2(Tpâ²(NH))Pt(η2 CH2CHCH3)Me][B(ArF)4].82
Related Topics
Physical Sciences and Engineering
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Authors
Katherine D. Lavoie, Bryan E. Frauhiger, Peter S. White, Joseph L. Templeton,