Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1322022 | Journal of Organometallic Chemistry | 2012 | 6 Pages |
Abstract
⺠(p-Cymene)Ru2(μ-S2)(S2C2B10H10)2 (1) plus (cyclo-C6H10)(OH)CCH led to two isomers in 1:1. ⺠Both isomers can readily lose one water in boiling CHCl3 to yield two products. ⺠Reaction of 1 with PhC(O)CCH led to an additional Ru(II)(18e)/Ru(I)(19e) species. ⺠We observed the charge changes from 16e Ru(IV) to 18e Ru(II) and to unusual 19e Ru(I).
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Jiurong Hu, Xiao Tang, Guifeng Liu, Qibai Jiang, Dandan Duanmu, Yizhi Li, Hong Yan,