| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1322181 | Journal of Organometallic Chemistry | 2015 | 4 Pages |
•An unsymmetric disilane ligand (SiH3) (SiMeBut2).•A rare and stable complex {(SiH2) (SiMeBut2)}(H)PtⅡ(dcpe).•One of the very few examples of disilanylplatinum hydride complexes.
Treatment of the unsymmetric disilane (SiH3) (SiMeBut2) (1) containing one Si–Si single bond with Pt(dcpe) (PEt3)2 (dcpe = Cy2PCH2CH2PCy2) in the ratio of 1:1 leads to a stable disilanylplatinum hydride complex {(SiH2) (SiMeBut2)}(H)– PtⅡ(dcpe) (2), which is one of the very few examples of bis(phosphine) (hydrido) platinum(Ⅱ) complexes bearing silyl ligands with Si–Si single bonds structurally characterized by single crystal X-ray analysis and multinuclear NMR spectroscopic studies.
Graphical abstractTreatment of the unsymmetric disilane (SiH3)(SiMeBut2) with Pt(dcpe)(PEt3)2 leads to a stable disilanylplatinum hydride complex {(SiH2)(SiMeBut2)}(H)PtⅡ(dcpe), which is one of the very few examples of bis(phosphine)(hydrido) platinum(Ⅱ) complexes bearing silyl ligands with Si–Si single bonds.Figure optionsDownload full-size imageDownload as PowerPoint slide
