| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1322188 | Journal of Organometallic Chemistry | 2012 | 8 Pages |
Abstract
⺠Modification of co-ligand from CO to PMe3 or PF3 yields a lower energy barrier. ⺠Larger Ï-acidic ligands may enhance selectivity for substituted olefins. ⺠Replacing Os with Ru lowers/raises barriers to C-H activation/ethylene insertion. ⺠Changing Tp to Mp results in a viable catalyst for ligands less donating than PMe3.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Glenn R. Morello, Thomas R. Cundari, T. Brent Gunnoe,