| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1322248 | Journal of Organometallic Chemistry | 2011 | 4 Pages |
The reaction of cyanuric chloride and two disubstituted derivatives with [Pd(PPh3)4] is described, leading to the trans-triazinyl complexes [(PPh3)2Pd(C3N3R2)Cl] 2a–c (R = Ph (a), t-Bu (b), Cl (c)) in good to excellent yield via oxidative addition. The complexes were fully characterized including X-ray structure determination.
Graphical abstractThe reaction of cyanuric chloride and two disubstituted derivatives with [Pd(PPh3)4] is described, leading to the trans-triazinyl complexes [(PPh3)2Pd(C3N3R2)Cl] 2a–c (R = Ph (a), t-Bu (b), Cl (c)) in good to excellent yield via oxidative addition. The complexes were fully characterized including X-ray structure determination.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Oxidative addition of chlorotriazines to Pd(0) leads to square planar Pd(II) complexes. ► Crystal structures have been determined for 2 complexes. ► Short Pd–C bonds are found compared to related complexes.
