Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1322322 | Journal of Organometallic Chemistry | 2014 | 6 Pages |
Abstract
The initiation step, self metathesis of β-pinene and its cross metathesis with (Z)-3-methylpent-2-ene have been modeled. Initiation leads to the formation of tertiary metalacarbene which undergoes nonproductive metathesis reaction with β-pinene. The self-metathesis productive reaction path is inhibited by kinetic and thermodynamic factors.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Alba Acevedo, Serguei Fomine, Selena Gutiérrez, Mikhail A. Tlenkopatchev,