Article ID Journal Published Year Pages File Type
1322438 Journal of Organometallic Chemistry 2011 5 Pages PDF
Abstract

Reaction of a 1:1 mixture of (L)AuCl [L = P(t-Bu)2o-biphenyl or IPr] and AgSbF6 with internal alkynes led to isolation of the corresponding cationic, two-coordinate gold π-alkyne complexes in ≥ 90% yield. Equilibrium binding studies show that the binding affinities of alkynes to gold(I) are strongly affected by the electron density of the alkyne and to a lesser extent on the steric bulk of the alkyne. These substituent effects on alkyne binding affinity are greater than are the differences between the inherent binding affinities of alkynes and alkenes to gold(I).

Graphical abstractReaction of (L)AuCl [L = P(t-Bu)2o-biphenyl or IPr] with AgSbF6 and an internal alkyne led to isolation of the corresponding cationic, two-coordinate gold π-alkyne complexes in ≥ 90% yield. Equilibrium binding studies show that the binding affinities of alkynes to gold(I) are strongly affected by the electron density of the alkyne and to a lesser extent on the steric bulk of the alkyne.Figure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights►Cationic gold(I) π-alkyne complexes synthesized and characterized. ►Alkyne binding affinity strongly affected by substitution. ►Alkyne and alkene binding affinity to gold(I) do not differ significantly.

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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