| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1322451 | Journal of Organometallic Chemistry | 2011 | 7 Pages |
Abstract
⺠The [Nb2F11]â ion provides great inertness to radical cations of monocyclic arenes. ⺠The inertness increases on decreasing the steric hidrance of the ring substituents. ⺠EPR spectra of the salts evidence coupling with the anion nuclei. ⺠UV-Vis spectra show a anion-to-cation charge-transfer band. ⺠The benzene salt is obtained in low yield for thermodynamic reasons.
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Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Room-temperature long-lived [Nb2F11]â salts of radical cations of simple arenes: EPR, UV-Vis and DFT results](/preview/png/1322451.png "First Page Preview: Room-temperature long-lived [Nb2F11]â salts of radical cations of simple arenes: EPR, UV-Vis and DFT results")
Authors
Fabio Marchetti, Guido Pampaloni, Calogero Pinzino,