| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1322489 | Journal of Inorganic and Nuclear Chemistry | 2017 | 5 Pages |
Abstract
The initial product of the interaction of osmium (VIII) oxide and ammonia, OsO4·NH3, is shown to undergo dehydration to nitrido-osmic-(VIII) acid which in turn is converted to the trinuclear species Os3N7O9H21 or its partially dehydrated analogue, Os3N7O7H17. Infra-red spectral, thermogravimetric analysis, and other data are used to elucidate the structure of Os3N7O9H21, including its conversion to a related complex Os3N5O5H7 by dehydration and deammoniation.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
