| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1322591 | Journal of Organometallic Chemistry | 2011 | 4 Pages |
Abstract
⺠A new benzylidene-bridged heterodinuclear complex (Cy3P)(OC)2Ru(μ-CHPh)(μ-Cl)Mn(CO)3(PCy3) was synthesized by metathesis reaction of RuCl2(PCy3)2(CHPh) with Na+[Mn(CO)5]â. ⺠They are characterized by NMR and X-ray structure analysis. ⺠Highly congested structure hinders rotation of the phenyl substituent on the μ-carbene carbon, showing fluxionality in 1H NMR.
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Authors
Shin-ichi Tanaka, Nobuyuki Komine, Masafumi Hirano, Sanshiro Komiya,