| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1322623 | Journal of Organometallic Chemistry | 2010 | 9 Pages |
Silylated functionalized arylboronic acids were converted into corresponding iodinated arylboronic acids in good yields via the electrophilic ipso-desilylation effected with iodine chloride in refluxing CHCl3. Disilylated arylboronic acids were susceptible to diiodination. In addition, the structural characterization and reactivity of a novel sterically hindered ortho-silylated diarylborinic ester were reported. The potential of selected iodinated phenylboronic acids as monomers for the Suzuki–Miyaura cross-coupling polymerization was demonstrated.
Graphical abstractNovel functionalized iodophenylboronic acids were prepared by the ipso-desilylation protocols starting with silylated arylboronic acids.Figure optionsDownload full-size imageDownload as PowerPoint slide
