Synthesis of siloxy-modified second generation Hoveyda–Grubbs catalysts and their catalytic activity

Efficient syntheses of the first ruthenium alkylidene complexes bearing siloxide ligands are described. Second generation Hoveyda–Grubbs catalyst is shown to undergo efficient functionalization with a number of potassium silanolates to give disiloxy derivatives. The complexes obtained are found catalytically active in selected metathesis transformations.

Graphical abstractEfficient syntheses of the first ruthenium alkylidene complexes bearing siloxide ligands are described. The complexes obtained exhibit catalytic activity in selected metathesis transformations.Figure optionsDownload full-size imageDownload as PowerPoint slide