Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1322822 | Journal of Organometallic Chemistry | 2013 | 5 Pages |
Abstract
A series of CpNi(NHC) halide complexes are synthesized from Cp2Ni and the azolium halide. Their X-ray structures and electrochemistry are reported.
Graphical abstractA series of CpNi(NHC) halide complexes are synthesized from Cp2Ni and the azolium halide; their X-ray structures and electrochemistry are reported.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► A series of cyclopentadienyl Ni NHC complexes has been synthesized. ► The electrochemical analysis revealed rich oxidative responses. ► Donating NHCs permit low-potential access to high oxidation states.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Oana R. Luca, Bennett A. Thompson, Michael K. Takase, Robert H. Crabtree,