| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1322901 | Journal of Organometallic Chemistry | 2016 | 7 Pages |
•The asymmetric activation of the flexible biphenyldiamidophosphite moiety is reported.•High diastereomeric prevalence is obtained in the formation of Rh-complexes.•Both monosubstituted and disubstituted Rh-complexes can be obtained.
A tropos deoxcholic acid derived diamidophosphite was synthesised starting from deoxycholic acid and N,N′-dimethyl-2,2′-diamino-1,1′biphenyl and its stereodinamic characteristics were assessed by VT-NMR spectroscopy. The capability of the diamidophosphite to act as Rh-ligand was investigated in the formation of ionic as well as covalent Rh-complexes. The stereodinamic properties of these complexes were studied by VT-NMR spectroscopy.
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