Article ID Journal Published Year Pages File Type
1323068 Journal of Organometallic Chemistry 2016 8 Pages PDF
Abstract

•Au(I) complexes with di(N-heterocyclic carbene) ligands.•Bis(imidazolium) salts bearing long-chain alkyl substituents.•Study on thermotropic properties of bis(imidazolium) salts and carbene complexes.•Bis(imidazolium) salts behave as thermotropic liquid crystals.

New propylene bridged bis(imidazolium) salts bearing at the wingtip positions a benzyl group functionalised with one or two long alkyl chains, as well as the corresponding dinuclear N-heterocyclic dicarbene gold(I) complexes of general formula [Au2(RIm–(CH2)3–ImR)2](X)2 (X = Br, PF6, BF4) have been synthesised and thermally characterised. All the compounds are stable up to 200 °C and the bis(imidazolium) salts [H2(RIm–(CH2)3–ImR)](X)2 (X = Br, PF6) behave as thermotropic liquid crystals in the temperature range 100–200 °C. By contrast, only the gold(I) diNHC complexes with eight aliphatic chains present mesomorphism, whereas those with four chains show numerous crystalline phases with structural disorder and presumably modified Au–Au distances, as indicated by solid state emission properties.

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Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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