| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1323085 | Journal of Organometallic Chemistry | 2008 | 9 Pages |
Abstract
Four new phosphazirconocenes were prepared, and a crystal structure was obtained demonstrating unambiguously the meso configuration. Propylene polymerization was chosen to provide by inference insight into the phosphametallocene rotational dynamics. Phosphazirconocene 9 was found to produce isotactic and atactic polypropylene. A model based on computations is proposed.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
William P. Freeman, Yi Joon Ahn, T. Keith Hollis, J. Andrew Whitaker, Victor C. Vargas, Ramel J. Rubio, Karen D. Alingog, Eike B. Bauer, Fook S. Tham,