| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1323276 | Journal of Organometallic Chemistry | 2015 | 8 Pages |
Abstract
The reaction of the 16e species (MeCp)CoS2C2B10H10, methyl propiolate and cyclopentadiene at ambient temperature has led to the B-C coupled complex between Cp ligand and carborane cage. An unusual in situ-generated 3e donor o-carborane dithio ligand appears which bears a moiety formed by a [4Â +Â 2] Diels-Alder cycloaddition. MeCp remains intact on the metal and the applied free CpH is oxidized to metal for further Diels-Alder addition with the olefinic unit.243
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Authors
Rui Zhang, Lin Zhu, Zhenzhong Lu, Hong Yan,