Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1323291 | Journal of Organometallic Chemistry | 2015 | 6 Pages |
Abstract
The room-temperature demethylation of the SMe2 group in reaction of (η-9-SMe2-7,8-Me2-7,8-C2B9H8)MBr2 (M = Rh, Ir) with CpTl is promoted by the bromide anion coordinated with metal atom. Demethylation by free halide ions is very slow at room temperature.294
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Mikhail M. Vinogradov, Yulia V. Nelyubina, Dmitry A. Loginov, Alexander R. Kudinov,