| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1323316 | Journal of Organometallic Chemistry | 2012 | 5 Pages |
The synthesis of rhenacycles [Re(CO)3(L){Ph2P(S)NP(S)Ph2-κ2S}] L = PPh3, (1), PMePh2 (2), PMe2Ph, (3), and PMe3, (4) by a straightforward high yield procedure is described. All new inorganic complexes (1)–(4) were characterized in solution and in the solid state.
Graphical abstractThree routes for the preparation of complexes [Re(CO)4(PR3){Ph2P(S)NP(S)Ph2-κ2S}] PR3=PPh3 (1), PMePh2 (2), PMe2Ph (3), and PMe3 (4) were explored. All new inorganic rhenacycles (1)–(4) were characterized in solution and in solid state.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Reaction chemistry of dithioimidodiphosphinato towards rhenium carbonyls and phosphines. ► High yields synthesis of a family of rhenacycles. ► Solution and solid state characterization of new rhenacycles.
