Article ID Journal Published Year Pages File Type
1323356 Journal of Organometallic Chemistry 2008 6 Pages PDF
Abstract

Optically active highly hindered half-sandwich ruthenium(II) compounds with C2-symmetric cyclopentadienyl ligands were synthesized from the ligand precursors, 4 and 5, which were derived from (−)-β-pinene. Thus, the reaction of the ligands with triruthenium dodecacarbonyl produced ruthenium compounds, 10 and 11, after oxidative treatment. These compounds were characterized by single crystal X-ray crystallography.

Graphical abstractOptically active highly hindered half-sandwich ruthenium(II) compounds with C2-symmetric cyclopentadienyl ligands were synthesized from the ligand precursors, which were derived from (−)-β-pinene. Thus, the reaction of the ligands with triruthenium dodecacarbonyl produced ruthenium compounds, after oxidative treatment. These compounds were characterized by single crystal X-ray crystallography.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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