| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1323418 | Journal of Organometallic Chemistry | 2012 | 9 Pages |
Palladium(II) complexes of the general formulae [PdCl2(P∧N)] and [Pd(Me)Cl(P∧N)] were obtained from bidentate ligands bearing phosphine and imine donor groups. The complexes were shown to be highly active catalysts for the Suzuki–Miyaura cross-coupling reaction. The complexes are tolerant of a wide variety of reaction conditions such as solvent, choice of base as well as substituents on both arylboronic acids and aryl halides.
Graphical abstractPalladium(II) complexes of the general formulae [PdCl2(P∧N)] and [Pd(Me)Cl(P∧N)] were obtained from bidentate ligands bearing phosphine and imine donor groups. The complexes were shown to be highly active catalysts for the Suzuki–Miyaura cross-coupling reaction. The complexes are tolerant of a wide variety of reaction conditions such as solvent, choice of base as well as substituents on both arylboronic acids and aryl halides.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Bidentate iminophosphine ligands have been prepared. ► Neutral palladium(II) chloromethyl complexes were synthesized containing iminophosphine ligands. ► The palladium complexes have been used in Suzuki–Miyaura coupling reactions. ► The catalysts are highly active and tolerant of various reaction conditions.
