| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1323505 | Journal of Organometallic Chemistry | 2012 | 5 Pages |
Abstract
The compound, [Ru(dppe)2(CH3CN)Cl][BPh4] (1) has been synthesized from the precursor complex, [(PPh3)2Ru(CH3CN)3Cl][BPh4]. The complex has been structurally characterized. This complex has been found to be an efficient catalyst for the anti-Markovnikov addition of carboxylic acids to alkynes.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Synthesis and structure of [Ru(dppe)2(CH3CN)Cl][BPh4]. ► Regioselective anti-Markovnikov addition of carboxylic acids to alkynes. ► Synthesis of Z-vinyl ester catalyzed by [Ru(dppe)2(CH3CN)Cl][BPh4].
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Synthesis and structure of [Ru(dppe)2(CH3CN)Cl][BPh4] and its catalytic application to anti-Markovnikov addition of carboxylic acids to terminal alkynes](/preview/png/1323505.png "First Page Preview: Synthesis and structure of [Ru(dppe)2(CH3CN)Cl][BPh4] and its catalytic application to anti-Markovnikov addition of carboxylic acids to terminal alkynes")
Authors
Uttam Kumar Das, Manish Bhattacharjee,