Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1323636 | Journal of Organometallic Chemistry | 2014 | 4 Pages |
Abstract
•Planar, tetranuclear Re(I) based coordination complex of tetrahydroxy-p-benzoquinone.•Tetrametallic complex was assembled in the absence of ancillary ligand in one step.•Tetrahydroxy-p-benzoquinone in complex illustrates an unusual octa-dentate binding mode.
A new tetrametallic coordination complex of tetrahydroxy-p-benzoquinone (THBQ = C6O2(OH)4) has been synthesized by a single step reaction of THBQ with Re2(CO)10 in the absence of an ancillary ligand. This is only the second report on the synthesis of a discrete, planar, tetrametallic coordination complex containing THBQ4− anion and its crystal structure.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Deepak Gupta, Bhaskaran Shankar, Palani Elumalai, Ramasamy Shanmugam, Shaikh M. Mobin, Fritz Weisser, Biprajit Sarkar, Malaichamy Sathiyendiran,