Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1323645 | Journal of Organometallic Chemistry | 2014 | 6 Pages |
•Facile synthesis of two new triazole-modified cyrhetrene complexes.•Characterization by NMR, IR, UV–vis, mass spectrometry and X-ray crystallography.•Redox behaviour of triazole–cyrhetrene complexes differs from cymantrene analogues.
We report the synthesis and characterization of two new cyclopentadienyl tricarbonyl rhenium(I) (cyrhetrene) complexes modified with a 1,4-disubstituted 1,2,3-triazole moiety. The two compounds, (η5-[4-phenyltriazol-1-yl]cyclopentadienyl) tricarbonyl rhenium(I), and (η5-[4-(4-aminophenyl)triazol-1-yl]cyclopentadienyl) tricarbonyl rhenium(I), were structurally characterized using 1H and 13C NMR, ATR-IR spectroscopy, UV–vis spectroscopy, mass spectrometry and X-ray crystallography where appropriate. The electrochemical behaviour of these two cyrhetrene–triazole complexes was explored using cyclic voltammetry, whereupon we observed that irreversible oxidation of the pendant 4-substituted-triazole moiety occurs before any electron transfer at the metal centre. This redox behaviour is in stark contrast to that of the analogous manganese(I) cymantrene–triazole derivatives, recently reported by our group.
Graphical abstractTwo new cyclopentadienyl tricarbonyl rhenium(I) (cyrhetrene) complexes modified with a 1,4-disubstituted 1,2,3-triazole moiety were synthesized and characterized.Figure optionsDownload full-size imageDownload as PowerPoint slide