Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1323654 | Journal of Organometallic Chemistry | 2014 | 5 Pages |
•Synthesis and structure of [Ru(PPh3)2(bipy)(MeCN)Cl][BPh4].•Regioselective and stereoselective allylation of phenols.•Synthesis of allyl ethers catalyzed by [Ru(PPh3)2(bipy)(MeCN)Cl][BPh4].
The compound, [Ru(PPh3)2(bipy)(MeCN)Cl][BPh4] (1) has been synthesized from the precursor complex, [Ru(bipy)(PPh3)2Cl2]. The complex has been structurally characterized. This complex has been found to be an efficient catalyst for the regioselective allylation of phenols.
Graphical abstractThe compound, [Ru(PPh3)2(bipy)(MeCN)Cl][BPh4] (1) has been synthesized from the precursor complex, [Ru(bipy)(PPh3)2Cl2]. The complex has been structurally characterized. This complex has been found to be an efficient catalyst for the regioselective allylation of phenols.Figure optionsDownload full-size imageDownload as PowerPoint slide