| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1323744 | Journal of Organometallic Chemistry | 2006 | 6 Pages |
Abstract
Tungsten alkylidene complex Me3Ge-CHW(NAr)(OCMe2CF3)2 (1) (Ar=2,6-Pr2iC6H3) and metallocycle [CH(GeMe3)CH(GeMe3)CH2]W(NAr)(OR)2 (2) were synthesized and structurally characterized. The both compounds 1 and 2 were found to have low activity in metathesis of 1-hexene and high activity in ROMP of cyclooctene and norbornene.
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Synthesis, structures and catalytic properties of germanium-containing tungsten alkylidene complex Me3Ge-CHW(NAr)(OR)2 and metallacycle [CH(GeMe3)CH(GeMe3)CH2]W(NAr)(OR)2](/preview/png/1323744.png "First Page Preview: Synthesis, structures and catalytic properties of germanium-containing tungsten alkylidene complex Me3Ge-CHW(NAr)(OR)2 and metallacycle [CH(GeMe3)CH(GeMe3)CH2]W(NAr)(OR)2")
Authors
Leonid N. Bochkarev, Yulia E. Begantsova, Andrey L. Bochkarev, Natalia E. Stolyarova, Irina K. Grigorieva, Irina P. Malysheva, Galina V. Basova, Elena O. Platonova, Georgii K. Fukin, Evgenii V. Baranov, Yurii A. Kurskii, Gleb A. Abakumov,