| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1323841 | Journal of Organometallic Chemistry | 2006 | 16 Pages |
Abstract
Insertion of alkynes into the ruthenium-aminocarbyne bond generate diruthenium bridging vinyliminium complexes. The μ-vinyiliminium ligands undergo hydride addition (by NaBH4) at the iminium carbon (Cα), or at the adjacent Cβ, or can be deprotonated (by NaH) at the Cβ-H position.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Luigi Busetto, Fabio Marchetti, Stefano Zacchini, Valerio Zanotti,