Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1323883 | Journal of Organometallic Chemistry | 2011 | 4 Pages |
Abstract
Allene reacts with the benzothiazolide clusters [Os3(CO)9(μ3-NSC7H3R)(μ-H)] (R = H, Me) to afford the bridging allyl complexes [Os3(CO)7(μ-CO)2(μ-NSC7H3R)(μ-η1:η2:η1-CH2CHCH2)] resulting from insertion of allene into the metal–hydride. Both have been crystallographically characterized and differ with respect to the relative arrangement of allyl and benzothiazolide at the triosmium centre.
Graphical abstractReactivity of electron-deficient triosmium benzothiazolide clusters towards allene is investigated.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Reactions of electron-deficient triosmium-hydride clusters with allene. ► Insertion of allene into metal–hydride. ► Formation of bridging allyl ligand.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Md. Iqbal Hossain, Shishir Ghosh, Graeme Hogarth, G.M. Golzar Hossain, Shariff E. Kabir,