Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1323905 | Journal of Organometallic Chemistry | 2014 | 5 Pages |
•tert-Butyl group transfer was observed between t-BuBNAH and (η6-arene)Mn(CO)3+ complexes without a radical initiator.•Hantzsch ester with isopropyl substituent at the C4 position undergo isopropyl transfer to (η6-benzene)Mn(CO)3+ complex.•The substituents on the aromatic ring significantly influence the reactivity and chemoselectivity.•The present alkyl group transfer reactions exhibit different reactivity pattern from organomercurials and indium system.
The direct tert-butyl group transfer was observed between t-BuBNAH and (η6-arene)Mn(CO)3+ complexes in reflux acetonitrile without a radical initiator, and the corresponding tert-butyl radical addition products were achieved. The substituents on the aromatic ring significantly influence the reactivity and chemoselectivity. The electron-withdrawing group helps to promote the reactions. The radical inhibition experiment indicated that the reaction is probably a radical chain process initiated by single electron transfer.
Graphical abstractThe direct tert-butyl group transfer was observed between t-BuBNAH and (η6-arene)Mn(CO)3+ complexes in reflux acetonitrile without a radical initiator, and the corresponding tert-butyl radical addition products were achieved.Figure optionsDownload full-size imageDownload as PowerPoint slide