Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1323923 | Journal of Organometallic Chemistry | 2006 | 8 Pages |
Abstract
Sb-chirogenic organoantimony compounds bearing heteroatom groups on the o-position of an aryl group have been prepared by nucleophilic displacement of the ethynyl moiety on (1-naphthyl)(phenylethynyl)(p-tolyl)stibane with aryllithium reagents. Optical resolution of the racemic compounds thus synthesized was achieved via separation of a diastereomeric mixture of their palladium complexes.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Shuji Yasuike, Yoshihito Kishi, Shin-ichiro Kawara, Kentaro Yamaguchi, Jyoji Kurita,