Article ID Journal Published Year Pages File Type
1323992 Journal of Organometallic Chemistry 2006 6 Pages PDF
Abstract

Polymer-supported alkoxycarbonylcyclopentadienyl rhodium(I) complexes have been obtained through immobilization of [Rh{C5H4CO2(CH2)2O2C-Im}(NBD)] (2) (Im = imidazole) on an (aminomethyl)polystyrene resin. An alternative approach toward the grafting of [Rh{C5H4CO2(CH2)2OH}(NBD)] (1) on a Wang resin has been also developed. Spectroscopic characterization of all the new functionalized resins with particular accent on ICP-OES measurements is presented and discussed.

Graphical abstractThe facile synthesis of polymer-supported alkoxycarbonylcyclopentadienyl rhodium(I) complexes obtained through immobilization of [Rh{C5H4CO2(CH2)2O2C-Im}(NBD)] (2) (Im = imidazole) on an (aminomethyl)polystyrene resin is reported. An alternative approach toward the grafting of [Rh{C5H4CO2(CH2)2OH}(NBD)] (1) on a Wang resin is also discussed.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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