| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1323995 | Journal of Organometallic Chemistry | 2006 | 9 Pages |
Abstract
The p-anisyl(1,2,3-tri-tert-butylcycloprop-2-en-1-yl)germylene (2) was generated by reduction of the corresponding dichlorogermane. DFT calculations revealed that the cis-2-germabicyclo[1.1.0]butane-like structure cis-5 is 8.0Â kJ/mol more stable than cis-2. The NBO analysis revealed that cis-5 has a 2-germabicyclo[1.1.0]butane diradical character.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Shinobu Tsutsui, Hiromasa Tanaka, Eunsang Kwon, Shigeki Matsumoto, Kenkichi Sakamoto,