| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1324074 | Journal of Organometallic Chemistry | 2014 | 4 Pages |
Abstract
Asymmetric cycloaddition reaction between 3,4-dimethyl-1-phenylarsole and ethyl vinyl ketone was promoted by the palladium complex containing ortho-metalated (S)-[1-(dimethylamino)ethyl]naphthalene as the chiral auxiliary. The keto group in the resulting arsanorbornene cycloadducts could be located stereospecifically in the endo or exo position by controlling the electronic properties of the organopalladium promoter.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Mengtao Ma, Zhijuan Yu, Lijun Zhu, Sumod A. Pullarkat, Pak-Hing Leung,